Potassium dicyanoargentate(I) 1,4,7,10,13,16-hexaoxacyclooctadecane

被引：5
|
作者：
Schlueter, JA [1 ]
Geiser, U [1 ]
机构：
[1] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2003年 / 59卷
关键词：
D O I：
10.1107/S0108270103014318
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structure of the title compound, K[Ag(CN)(2)].-C12H24O6, conventionally denoted K(18-crown-6)Ag(CN)(2), where 18-crown-6 is 1,4,7,10,13,16-hexaoxacyclooctadecane, is characterized by closely packed linear chains formed by the coordination of the nitrile N atoms of the [Ag(CN)(2)](-). anions to the K+ cations. The K atoms lie on centers of inversion and are additionally bound to the six O atoms of the crown ether.
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页码：M325 / M327
页数：3
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