Continuous flow synthesis of poly(acrylic acid) via free radical polymerisation

被引：26
|
作者：
Brocken, Laurens [1 ]
Price, Paul D. [2 ]
Whittaker, Jane [2 ]
Baxendale, Ian R. [1 ]
机构：
[1] Univ Durham, Dept Chem, South Rd, Durham DH1 3LE, England
[2] Unilever R&D Port Sunlight, Quarry Rd East, Wirral CH63 3JW, Merseyside, England
来源：
REACTION CHEMISTRY & ENGINEERING | 2017年 / 2卷 / 05期
基金：
英国工程与自然科学研究理事会;
关键词：
RAFT POLYMERIZATION; MULTISTEP SYNTHESIS; MASS-SPECTROMETRY; NMR-SPECTRA; CHEMISTRY; REACTOR; OPTIMIZATION; SPECTROSCOPY; SUPPRESSION; KINETICS;
D O I：
10.1039/c7re00063d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The free radical polymerisation of aqueous solutions of acrylic acid (1) has been studied using a continuous flow reactor to quickly screen reaction parameters such as temperature, residence time, monomer- and initiator concentration. The experimental data sets produced established a theoretical basis for conducting scale up processes to efficiently produce larger quantities of poly(acrylic acid) delivered with good control over the molecular weight and dispersity.
引用
收藏
页码：662 / 668
页数：7
相关论文
共 50 条
  • [21] Synthesis of poly(ethylene-co-acrylic acid) via a tandem hydrocarboxylation/hydrogenation of poly(butadiene)
    Wiggins, Kelly M.
    Bielawski, Christopher W.
    POLYMER CHEMISTRY, 2013, 4 (07) : 2239 - 2245
  • [22] Poly(acrylic acid)/palygorskite microgel via radical polymerization in aqueous phase for reinforcing poly(vinyl alcohol) hydrogel
    Wang, Dafeng
    Zhu, Longxiang
    Qiu, Jianhui
    Zhu, Ping
    APPLIED CLAY SCIENCE, 2020, 185
  • [23] Poly(vinyl alcohol) and poly(dimethylsiloxane)-based interpenetrating polymer networks via radical polymerisation
    Coelho, Elidiane Carvalho
    dos Santos, Daniela Pereira
    Ciuffi, Katia Jorge
    Ferrari, Jefferson Luis
    Ferreira, Beatriz Alves
    Schiavon, Marco Antonio
    JOURNAL OF POLYMER RESEARCH, 2014, 21 (09)
  • [24] Poly(vinyl alcohol) and poly(dimethylsiloxane)-based interpenetrating polymer networks via radical polymerisation
    Elidiane Carvalho Coelho
    Daniela Pereira dos Santos
    Kátia Jorge Ciuffi
    Jefferson Luis Ferrari
    Beatriz Alves Ferreira
    Marco Antonio Schiavon
    Journal of Polymer Research, 2014, 21
  • [25] Chemical Modification of Biomass Okara Using Poly(acrylic acid) through Free Radical Graft Polymerization
    Zhu, Jingling
    Song, Xia
    Tan, Wee Kee
    Wen, Yuting
    Gao, Zhengyang
    Ong, Choon Nam
    Loh, Chiang Shiong
    Swarup, Sanjay
    Li, Jun
    JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2020, 68 (46) : 13241 - 13246
  • [26] Synthesis of poly(acrylic acid) coated magnetic nanospheres via a multiple polymerization route
    Li, Kai
    Chen, Kaimin
    Wang, Qiaoling
    Zhan, Ying
    Gan, Wenjun
    ROYAL SOCIETY OPEN SCIENCE, 2019, 6 (07):
  • [27] Controlled synthesis of poly(vinyl alcohol)-poly(acrylic acid) copolymers via cobalt mediated radical polymerization of vinyl acetate initiated by V-70
    Tazehabadi, Mohammad Javad Mohammadi
    Ansari, Mojtaba
    Sabzevari, Alireza
    JOURNAL OF MOLECULAR STRUCTURE, 2025, 1331
  • [28] Synthesis and properties of semifluorinated block copolymers containing poly(ethylene oxide) and poly(fluorooctyl methacrylates) via atom transfer radical polymerisation
    Lim, KT
    Lee, MY
    Moon, MJ
    Lee, GD
    Hong, SS
    Dickson, JL
    Johnston, KP
    POLYMER, 2002, 43 (25) : 7043 - 7049
  • [29] Controlled poly(olefin)s via decarboxylation of poly(acrylic acid)
    Chapman, Robert
    Melodia, Daniele
    Qu, Jian-Bo
    Stenzel, Martina H.
    POLYMER CHEMISTRY, 2017, 8 (43) : 6636 - 6643
  • [30] The synthesis of poly(4,4′-biphenylene vinylene) and poly(2,6-naphthalene vinylene) via a radical chain polymerisation
    Van der Borght, M
    Adriaensens, P
    Vanderzande, D
    Gelan, J
    POLYMER, 2000, 41 (08) : 2743 - 2753
12345