Equilibrium Conditions of Ethane Hydrates in the Presence of Aqueous Solutions of Alcohols, Glycols, and Glycerol

被引:19
|
作者
Maekawa, Tatsuo [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Inst Georesources & Environm, Tsukuba, Ibaraki 3058567, Japan
来源
关键词
CARBON-DIOXIDE; DISSOCIATION CONDITIONS; HYDROGEN-SULFIDE; ETHYLENE-GLYCOL; METHANE; PROPANE; PREDICTIONS; WATER;
D O I
10.1021/je2010819
中图分类号
O414.1 [热力学];
学科分类号
摘要
Equilibrium conditions of ethane hydrates in aqueous solutions of methanol, ethanol, ethylene glycol, diethylene glycol, triethylene glycol, and glycerol were experimentally measured at temperatures ranging from (261.6 to 285.9) K and pressures of up to 3.12 MPa using an isochoric method. On a mass fraction basis, the inhibiting effect on ethane hydrate formation decreased in the following order: methanol > ethanol > ethylene glycol > glycerol approximate to diethylene glycol > triethylene glycol.
引用
收藏
页码:526 / 531
页数:6
相关论文
共 50 条
  • [21] VAPOR LIQUID EQUILIBRIUM IN AQUEOUS-SOLUTIONS OF VARIOUS GLYCOLS AND POLY(ETHYLENE GLYCOLS) .3. POLY(ETHYLENE GLYCOLS)
    HERSKOWITZ, M
    GOTTLIEB, M
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1985, 30 (02): : 233 - 234
  • [22] Gas hydrates of methane, ethane, propane, and carbon dioxide in the presence of single NaCl, KCl, and CaCl2 aqueous solutions: Experimental measurements and predictions of dissociation conditions
    Mohammadi, Amir H.
    Afzal, Waheed
    Richon, Dominique
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2008, 40 (12): : 1693 - 1697
  • [23] PECULIARITIES IN THE ESTABLISHMENT OF EQUILIBRIUM STATE IN DILUTED AQUEOUS SOLUTIONS OF GLYCEROL
    Bulavin, L. A.
    Gotsulskiy, V. Ya.
    Chechko, V. E.
    UKRAINIAN JOURNAL OF PHYSICS, 2014, 59 (07): : 689 - 695
  • [24] Equilibrium conditions hydrate dissociation for a ternary mixture of methane, ethane, and propane in aqueous solutions of ethylene glycol and electrolytes
    Sun, ZG
    Fan, SS
    Shi, L
    Guo, YK
    Guo, KH
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2001, 46 (04): : 927 - 929
  • [25] Experimental measurements and predictions of dissociation conditions for carbon dioxide and methane hydrates in the presence of triethylene glycol aqueous solutions
    Afkal, Waheed
    Mohammadi, Amir H.
    Richon, Dominique
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (05): : 2053 - 2055
  • [26] Equilibrium conditions for gas hydrates of methane and ethane mixtures in pure water and sodium chloride solution
    Maekawa, T
    GEOCHEMICAL JOURNAL, 2001, 35 (01) : 59 - 66
  • [27] Numerical prediction of phase equilibrium conditions of gas hydrates up to 200 MPa in the presence of sodium and calcium chloride solutions
    Mahiddini, Abderrahman
    Tchouar, Noureddine
    Aguedal, Hakim
    Ould-Kaddour, Fouzia
    Debab, Abedlekader
    PETROLEUM SCIENCE AND TECHNOLOGY, 2022, 40 (21) : 2557 - 2570
  • [28] Prediction of equilibrium conditions for gas hydrates in the organic inhibitor aqueous solutions using a thermodynamic consistency-based model
    Li, Siguang
    Li, Yanjun
    Yang, Longbin
    Han, Yang
    Jiang, Zhibin
    FLUID PHASE EQUILIBRIA, 2021, 544
  • [29] VAPOR LIQUID EQUILIBRIUM IN AQUEOUS-SOLUTIONS OF VARIOUS GLYCOLS AND POLY(ETHYLENE GLYCOLS) .1. TRIETHYLENE GLYCOL
    HERSKOWITZ, M
    GOTTLIEB, M
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1984, 29 (02): : 173 - 175
  • [30] Viscosities of cetylpyridinium bromide solutions (aqueous and aqueous KBr) in the presence of alcohols and amines
    David, SL
    Kumar, S
    KabirUdDin
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1997, 42 (01): : 198 - 201