Synthesis and X-ray single-crystal structure study of 5,5′-bis(silyl)-functionalized 3,3′-dibromo-2,2′-dithiophenes

被引：5

作者：

Baumgartner, T ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52074 Aachen, Germany

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2005年 / 19卷 / 07期

关键词：

oligothiophenes; electronic materials; synthesis; X-ray structure;

D O I：

10.1002/aoc.917

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A high-yield synthesis toward 5,5'-bis(silyl)-functionalized 3,3'-dibromo-2,2'-dithiophenes with very efficient work-up procedure is presented. The molecular structures of two silyl functionalized dibromo-dithiophenes in the solid state have been determined to investigate the structural influences of different functional groups on the degree of pi-conjugation within the dithiophene moieties, as well as their packing properties. The planar alignment of the tert-butyldimethylsilyl-functionalized dibromo-dithiophene shows a significantly higher degree of conjugation of the pi-system with a more favorable molecular packing than the skewed arrangement of the triisopropylsilyl-substituted species. Copyright (c) 2005 John Wiley & Sons, Ltd.

引用

页码：859 / 863

页数：5

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