Synthesis of 3,4'-dibromo-2,2'-bithiophene: A useful intermediate for 3,4'-disubstituted 2,2'-bithiophenes. X-ray molecular structure of 3,4'-dibromo-2,2'-bithiophene

被引：22

作者：

Antolini, L ^{[1
]}

Goldoni, F ^{[1
]}

Iarossi, D ^{[1
]}

Mucci, A ^{[1
]}

Schenetti, L ^{[1
]}

机构：

[1] UNIV MODENA, DIPARTIMENTO CHIM, I-41100 MODENA, ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 13期

关键词：

D O I：

10.1039/a700811b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first synthesis of 3,4'-dibromo-2,2'-bithiophene via metal-catalysed cross-coupling between a metallated and a halogenated thiophene derivative is described. An X-ray crystal structure of 3,4'-dibromo-2,2'-bithiophene is reported, 3,4'-Dibromo-2,2'-bithiophene was converted into corresponding bis(alkylsulfanyl) derivatives through bromine-lithium exchange, followed by reaction with two dialkyl disulfides (Me2S2 or Bu2S2). The H-1 and C-13 NMR data are discussed.

引用

页码：1957 / 1961

页数：5

共 50 条

[1] Synthesis of 3,4'-dibromo-2,2'-bithiophene: a useful intermediate for 3,4'-disubstituted 2,2'-bithiophenes. X-Ray molecular structure of 3,4'-dibromo-2,2'-bithiophene
[J]. J Chem Soc Perkin Trans 1, 13 (1957):
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