Cu and Au Metal-Organic Frameworks Bridge the Gap between Homogeneous and Heterogeneous Catalysts for Alkene Cyclopropanation Reactions

被引：97
|
作者：
Corma, Avelino [1 ]
Iglesias, Marta [2 ]
Llabres i Xamena, Francese X. [1 ]
Sanchez, Felix [3 ]
机构：
[1] Univ Politecn Valencia, Inst Tecnol Quim, CSIC, Valencia 46022, Spain
[2] CSIC, Inst Ciencia Mat Madrid, E-28049 Madrid, Spain
[3] CSIC, Inst Quim Organ Gen, E-28006 Madrid, Spain
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 32期
关键词：
copper; cyclopropanation; gold; heterogeneous catalysis; metal-organic frameworks; NETWORKS; SOLIDS; FUNCTIONALIZATION; COMPLEXES; DESIGN; BONDS; MOF; DFT;
D O I：
10.1002/chem.201000278
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The copper and gold metal organic frameworks (MOFs) [Cu-3(BTC)(2)(H2O)(3)](n), [Cu-3(BTC)(2)] (BTC=benzene-1.3.5-tricarboxylate). and IRMOF-3-SI-Au are active and reusable solid catalysts for the cyclopropanation of alkenes with high chemo- and diastereoselectivities Pus type of material gives better results than previous solid catalysts while working together with the homogeneous catalysts These MOFs can help to budge the gap between homogeneous and heterogeneous catalysis.
引用
收藏
页码：9789 / 9795
页数：7
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