The chemistry and biochemistry of vanadium and the biological activities exerted by vanadium compounds

被引：1195
|
作者：
Crans, DC [1 ]
Smee, JJ [1 ]
Gaidamauskas, E [1 ]
Yang, LQ [1 ]
机构：
[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA
来源：
CHEMICAL REVIEWS | 2004年 / 104卷 / 02期
关键词：
D O I：
10.1021/cr020607t
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The properties of vanadium and the biological activities exerted by vanadium compounds were analyzed. Vanadium compounds exhibited increasing numbers of enzyme activities. vanadate was placed by the vanadate-phosphate analogy in a central position to interact effectively with phosphorylases. The ability of V-complexes to act as peroxides, catalases, and nitrogenases was also analyzed. The reactions of V-compounds included redox proceses. But vanadate could not be a perfect transition state analogue and was not able to provide the entire binding affinity, anticipated for ideal analogue.
引用
收藏
页码：849 / 902
页数：54
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