Spin- orbit charge transfer intersystem crossing in perylenemonoimide- phenothiazine compact electron donor- acceptor dyads

被引:67
|
作者
Zhao, Yingjie [1 ]
Duan, Ruomeng [2 ]
Zhao, Jianzhang [1 ]
Li, Chen [2 ]
机构
[1] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, E-208 West Campus,2 Ling Gong Rd, Dalian 116024, Peoples R China
[2] Dongguan Univ Technol, Sch Environm & Civil Engn, 1 Daxue Rd, Dongguan, Guangdong, Peoples R China
关键词
TRIPLET-TRIPLET ANNIHILATION; PHOTON UP-CONVERSION; LIGHT PHOTOREDOX CATALYSIS; BODIPY-ANTHRACENE DYADS; TIME-RESOLVED EPR; SINGLET OXYGEN; PHOTODYNAMIC THERAPY; LOW-POWER; IRIDIUM PHOTOSENSITIZERS; METAL-COMPLEXES;
D O I
10.1039/c8cc07012a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The spin-orbit charge transfer intersystem crossing (SOCT-ISC) of perylenemonoimide-phenothiazine compact dyads was shown to depend on the molecular geometry and the vector dipole orientations of the two chromophores, and the dyads show high triplet state quantum yields (57%).
引用
收藏
页码:12329 / 12332
页数:4
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