Hydrothermal In Situ Synthesis of a Novel Three-dimensional Tetrazole Coordination Polymer with Manganese Ions

被引：14

作者：

Wang, Wei ^{[1
]}

Fu, Da-Wei ^{[1
]}

Xu, Xiong-Bin ^{[1
]}

Ye, Qiong ^{[1
]}

机构：

[1] Southeast Univ, Ordered Matter Sci Res Ctr, Nanjing 211189, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2011年 / 637卷 / 3-4期

基金：

中国国家自然科学基金;

关键词：

In situ hydrolysis; Tetrazoles; Hydrothermal synthesis; Dielectric properties; Manganese; METAL-ORGANIC FRAMEWORK; HUISGEN 1,3-DIPOLAR CYCLOADDITION; INORGANIC HYBRID MATERIALS; SECONDARY BUILDING UNITS; CLICK CHEMISTRY APPROACH; SUPRAMOLECULAR ISOMERISM; DIELECTRIC-CONSTANT; NETWORK; LIGANDS; DESIGN;

D O I：

10.1002/zaac.201000354

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reaction of benzotriazol-1-yl-acetonitrile and Mn(ClO4)(2)center dot 6H(2)O in the presence of NaN3 yielded almost colorless block-shaped crystals of a novel three-dimensional manganese coordination compound with benzotriazol-1-yl-acetic acid and 1-(1H-tetrazol-5-ylmethyl)-1H-benzotriazole ligands, which were obtained by in situ hydrolysis and 2+3 cyclo-additional reactions of the cyano group in Pyrex tube at 150 degrees C. In this compound azide, benzotriazol-1-yl-acetic acid, and 1-(1H-tetrazol-5-ylmethyl)-1H-benzotriazole as multidentate ligands coordinate to three crystallographically independent manganese atoms to form a novel three-dimensional coordination polymer. Dielectric measurements show no dielectric anomaly within the temperature range of 120 K to 300 K.

引用

页码：467 / 471

页数：5

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