Effect of Anions on Lithium Ion Conduction in Poly(ethylene carbonate)-based Polymer Electrolytes

被引：126
|
作者：
Tominaga, Yoichi [1 ]
Yamazaki, Kenta [1 ]
Nanthana, Vannasa [1 ]
机构：
[1] Tokyo Univ Agr & Technol, Grad Sch Bioapplicat & Syst Engn, Koganei, Tokyo 1848588, Japan
来源：
JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2015年 / 162卷 / 02期
基金：
日本科学技术振兴机构;
关键词：
PROPYLENE CARBONATE; COPOLYMERS; TRANSPORT; MIXTURES; NUMBERS; SALTS;
D O I：
10.1149/2.0211502jes
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Poly(ethylene carbonate)-based polymer electrolytes with lithium salts (LiX; X = TFSI, ClO4, BF4 and PF6) were prepared, and their lithium transference numbers (t(+)) were measured to make comparison between different anion radius and salt concentrations. The LiTFSI electrolytes had the highest t(+) and Li-ion conductivities of all samples at 80 degrees C; these values increased with increasing salt concentration. According to the results of FT-IR measurements for all concentrated samples, the changes of band fraction, which divide at around 1720 cm(-1) for carbonyl groups interact, with Li+ (C=O-Li+), are strongly related to the mobility of Li+ ions. (C) The Author(s) 2015. Published by ECS.
引用
收藏
页码：A3133 / A3136
页数：4
相关论文
共 50 条
  • [31] Single lithium-ion conducting polymer electrolytes based on poly[(4-styrenesulfonyl)(trifluoromethanesulfonyl)imide] anions
    Feng, Shaowei
    Shi, Dongyang
    Liu, Fang
    Zheng, Liping
    Nie, Jin
    Feng, Wengfang
    Huang, Xuejie
    Armand, Michel
    Zhou, Zhibin
    ELECTROCHIMICA ACTA, 2013, 93 : 254 - 263
  • [32] Decomposition reactions of ethylene carbonate based lithium-ion battery electrolytes.
    Campion, CL
    Li, WT
    Lucht, BL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U894 - U894
  • [33] Gel Polymer Electrolytes Based on Cross-Linked Poly(ethylene glycol) Diacrylate for Calcium-Ion Conduction
    Biria, Saeid
    Pathreeker, Shreyas
    Genier, Francielli S.
    Chen, Fu-Hao
    Li, Hansheng
    Burdin, Cameron, V
    Hosein, Ian D.
    ACS OMEGA, 2021, 6 (26): : 17095 - 17102
  • [34] ION-TRANSPORT IN THE POLYMER ELECTROLYTES FORMED BETWEEN POLY(ETHYLENE SUCCINATE) AND LITHIUM TETRAFLUOROBORATE
    DUPON, R
    PAPKE, BL
    RATNER, MA
    SHRIVER, DF
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1984, 131 (03) : 586 - 589
  • [35] Lithium ion conduction and ion-polymer interaction in PVdF-HFP based gel polymer electrolytes
    Isa, K. B. Md.
    Osman, Z.
    Arof, A. K.
    Othman, L.
    Zainol, N. H.
    Samin, S. M.
    Chong, W. G.
    Kamarulzaman, N.
    SOLID STATE IONICS, 2014, 268 : 288 - 293
  • [36] LITHIUM ELECTRODE BEHAVIOR IN POLY(ETHYLENE OXIDE)-LITHIUM PERCHLORATE POLYMER ELECTROLYTES
    FAUTEUX, D
    GAUTHIER, M
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1986, 133 (08) : C292 - C292
  • [37] Electrochemical properties of poly(tetra ethylene glycol diacrylate)-based gel electrolytes for lithium-ion polymer batteries
    Kim, HS
    Shin, JH
    Moon, SI
    Yun, MS
    JOURNAL OF POWER SOURCES, 2003, 119 : 482 - 486
  • [38] Lithium ion conductivity of blend polymer electrolytes based on borate polymers containing fluoroalkane dicarboxylate and poly(ethylene oxide)
    Aoki, T
    Konno, A
    Fujinami, T
    ELECTROCHIMICA ACTA, 2004, 50 (2-3) : 301 - 304
  • [39] Electrochemical characterization of poly (ethylene-co-methyl acrylate)-based gel polymer electrolytes for lithium-ion polymer batteries
    Kim, DW
    JOURNAL OF POWER SOURCES, 2000, 87 (1-2) : 78 - 83
  • [40] Dependence of Ion Dynamics on the Polymer Chain Length in Poly(ethylene oxide)-Based Polymer Electrolytes
    Chattoraj, Joyjit
    Knappe, Marisa
    Heuer, Andreas
    JOURNAL OF PHYSICAL CHEMISTRY B, 2015, 119 (22): : 6786 - 6791
12345