Solvothermal syntheses of Cu3P via reactions of amorphous red phosphorus with a variety of copper sources

被引：35
|
作者：
Aitken, JA
Ganzha-Hazen, V
Brock, SL [1 ]
机构：
[1] Duquesne Univ, Dept Chem & Biochem, Detroit, MI 48202 USA
[2] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2005年 / 178卷 / 04期
关键词：
solvothermal; hydrothermal; copper phosphide; transition metal phosphide; phosphide; pnictide; low temperature synthesis; microcrystalline;
D O I：
10.1016/j.jssc.2004.10.004
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Polycrystalline Cu3P was successfully prepared under a wide variety of solvothermal conditions. The reaction of red phosphorus with several copper sources (copper metal, copper (1) iodide, copper (I) chloride and copper (II) chloride) at 150-200 degrees C for 1-2 days in water produced Cu3P. Products were examined with powder X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy. Thermal analyses and optical spectroscopy were also performed. A detailed list of reaction conditions, products and impurity phases (where applicable) are reported. (c) 2004 Elsevier Inc. All rights reserved.
引用
收藏
页码：970 / 975
页数：6
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