Di-μ-thiocyanato-κ2N:S;κ2S:N-bis[bis(2methyl-1H-benzimidazole-κN3)(thiocyanato-κN)cadmium(II)]

被引：0
|
作者：
Shaker, Shayma A. [1 ]
Khaledi, Hamid [1 ]
Ali, Hapipah Mohd [1 ]
机构：
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
D O I：
10.1107/S1600536810042443
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Cd-2(NCS)(4)(C8H8N2)(4)], is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted square-pyramidal geometry around the Cd atom. In the crystal structure, two N-H center dot center dot center dot S hydrogen-bonding interactions occur, resulting in a three-dimensional polymeric structure. The apical 2-methylbenzimidazole ring and its symmetry-related counterpart are arranged in an antiparallel manner with a centroid-centroid separation of 3.6050 (14) angstrom, indicative of a pi-pi interaction.
引用
收藏
页码：M1464 / U1180
页数：10
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