Tetrakis(μ-2-methylbenzoato)bis[(2-methylbenzoic acid)copper(II)]

被引：4

作者：

Sunil, Abraham C. ^{[1
]}

Bezuidenhoudt, Barend C. B. ^{[1
]}

van Rensburg, J. Marthinus Janse ^{[1
]}

机构：

[1] Univ Orange Free State, Dept Chem, ZA-9300 Bloemfontein, South Africa

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536808006661

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title centrosymmetric dinuclear compound, [Cu-2(C8H7O2)(4)(C8H8O2)(2)], four o-toluate anions form a cage around two Cu atoms in a syn-syn configuration. Two more o-toluic acid molecules are apically bonded to the Cu atoms, which show a square-pyramidal coordination geometry. The acid H atoms are hydrogen bonded to the cage carboxyl O atoms [O center dot center dot center dot O = 2.660 (2) angstrom]. The molecular packing forms a puckered pseudo-hexagonal close-packed layer in the (h00) plane, with soft intermolecular H center dot center dot center dot H contacts (2.46-2.58 angstrom).

引用

页码：M553 / U380

页数：12

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