Nickel- or Iron-Catalyzed Cross-Coupling of Aryl Carbamates with Arylsilanes

被引：30
|
作者：
Shi, Wen-Juan [1 ,2 ]
Zhao, Hong-Wei [3 ]
Wang, Yang [1 ,2 ]
Cao, Zhi-Chao [1 ,2 ]
Zhang, Li-Sheng [1 ,2 ]
Yu, Da-Gang [1 ,2 ]
Shi, Zhang-Jie [1 ,2 ,4 ]
机构：
[1] Peking Univ, Coll Chem, Beijing Natl Lab Mol Sci, Beijing 10087, Peoples R China
[2] Peking Univ, Coll Chem, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 10087, Peoples R China
[3] Shanxi Univ, Coll Chem & Chem Engn, Taiyuan 030006, Shanxi, Peoples R China
[4] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2016年 / 358卷 / 15期
关键词：
arylsilanes; carbamates; C-O activation; copper(II) fluoride (CuF2); Hiyama reaction; C-O BOND; CARBON-OXYGEN BONDS; GRIGNARD-REAGENTS; METHYL ETHERS; MILD CONDITIONS; H BONDS; ORGANOSILICON REAGENTS; ORGANOBORON COMPOUNDS; ORGANOZINC REAGENTS; PHENOL DERIVATIVES;
D O I：
10.1002/adsc.201600590
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Aryl carbamates were for the first time applied as electrophiles in the cross-coupling with arylsilanes via nickel or iron catalysis to construct valuable biaryl compounds. This new coupling reaction features a good group tolerance and non-sensitivity to steric hindrance on both aryl carbamates and arylsilanes.
引用
收藏
页码：2410 / 2416
页数：7
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