High-pressure vapor-liquid equilibria, liquid densities, and excess molar volumes for the carbon dioxide+2-propanol system from (308.10 to 348.00) K

被引:16
|
作者
Khalil, Wael [1 ]
Coquelet, Christophe [1 ]
Richon, Dominique [1 ]
机构
[1] CNRS, CEP, TEP, FRE 2861, F-77305 Fontainebleau, France
来源
关键词
D O I
10.1021/je700321s
中图分类号
O414.1 [热力学];
学科分类号
摘要
Vapor-liquid equilibrium data and volumetric properties (density and excess molar volumes) of the carbon dioxide (1) + 2-propanol (2) system have been determined for seven molar compositions, z(1), close to 0.15, 0.20, 0.42, 0.60, 0.80, 0.95, and 0.97, using a vibrating tube densimeter, which takes advantage of a forced path mechanical calibration model. The Peng-Robinson equation of state including Panagiotopoulos and Reid mixing rules is used to correlate the data. Comparison of the new data with selected literature data and correlated results shows good consistency agreement, demonstrating the reliability of the data presented herein.
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页码:2032 / 2040
页数:9
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