The effect of Cu and Cu-humic acids on the adsorption of imazethapyr herbicide by montmorillonite clay

被引:2
|
作者
El Azzouzi, El Habib [1 ]
El Madani, Meryem [1 ]
Mekkaoui, Mohamed [1 ]
El Belghiti, Mohamed Alaoui [1 ]
El M'Rabet, Mohamadine [2 ]
Mountacer, Hafida [3 ]
El Hourch, Abderrahim [1 ]
Zrineh, Abdellah [1 ]
El Azzouzi, Mohammed [1 ]
机构
[1] Univ Mohammed V Agdal, Fac Sci Rabat, Ma Rabat, Morocco
[2] Inst Agron & Vet Hassan II APESA, Ma Rabat, Morocco
[3] Univ Hassan I, Fac Sci & Tech Settat, Ma Settat, Morocco
来源
关键词
Imazethapyr; adsorption isotherm; kinetic; pH; homoionic clays; humic acids; copper; COPPER(II) COMPLEXES; SOIL; IMAZAQUIN; IMAZAPYR; PH;
D O I
暂无
中图分类号
S3 [农学(农艺学)];
学科分类号
0901 ;
摘要
Adsorption of imazethapyr, an imidazolinone herbicide, was measured from dilute suspensions onto montmorillonite clay and complexes of montmorillonite with Cu and humic acid. Adsorption of imazethapyr was found to be greater for the Cu-montmorillonite and Cu-humic acid-montmorillonite complexes than by montmorillonite alone. Isotherm shape was similar for all supports studied. Adsorption of imazethapyr varied with pH for montmorillonite and for Cu-humic acid-montmorillonite complex. The pH had no apparent effect on imazethapyr adsorption to the Cu-montmorillonite complex. This might be due to imazethapyr retention at high pH by Cu ions linked to the clay. Imazethapyr adsorption kinetics was faster for Cu-montmorillonite (15 min) and Cu-humic acid-montmorillonite (30 min) than for montmorillonite (240 min). The copper-humic acid complexes with montmorillonite might be used to detoxify water contaminated with imazethapyr.
引用
收藏
页码:659 / 665
页数:7
相关论文
共 50 条
  • [41] USE OF C-14 FOR DETERMINATION OF ADSORPTION MECHANISMS OF HUMIC ACIDS ON MONTMORILLONITE
    VALLA, M
    JACQUIN, F
    GUCKERT, A
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE D, 1972, 274 (05): : 671 - &
  • [42] Comparative Study of the Adsorption of Pb (II), Cd (II) and Cu (II) in Natural Caulinotic and Montmorillonite Containing Clay
    Aragao, Debora M.
    Arguelho, Maria Lara P. M.
    Alves, Jose do Patrocinio H.
    Prado, Carolina M. O.
    ORBITAL-THE ELECTRONIC JOURNAL OF CHEMISTRY, 2013, 5 (03): : 157 - 163
  • [43] Microfiltration reinforced adsorption of humic acids onto modified Algerian clay
    Naceur, WM
    Messaoudene, NA
    Aggoun, A
    DESALINATION, 2003, 158 (1-3) : 271 - 276
  • [44] THE EFFECT OF PH ON THE RETENTION OF CU, PB, ZN AND CB BY CLAY HUMIC-ACID MIXTURES
    HATTON, D
    PICKERING, WF
    WATER AIR AND SOIL POLLUTION, 1980, 14 (DEC): : 13 - 21
  • [45] Effect of humic acids on the adsorption of paraquat by goethite
    Brigante, Maximiliano
    Zanini, Graciela
    Avena, Marcelo
    JOURNAL OF HAZARDOUS MATERIALS, 2010, 184 (1-3) : 241 - 247
  • [46] New insights into the effects of the herbicide imazethapyr on Cu(II) ecotoxicity to the aquatic unicellular alga Scenedesmus obliquus
    Chen, Hui
    Sheng, Xiaolin
    Wen, Yuezhong
    Zhang, Lijuan
    Bao, Hongliang
    Li, Lina
    Liu, Weiping
    AQUATIC TOXICOLOGY, 2013, 140 : 407 - 414
  • [47] Study of structure and properties of humic and fulvic acids.: II.: Study of adsorption of Cu2+ ions to humic acids extracted from lignite
    Klucáková, M
    Kaláb, M
    Pekar, M
    Lapcík, L
    JOURNAL OF POLYMER MATERIALS, 2002, 19 (03): : 287 - 294
  • [48] Effect of humic acid adsorption on the rheological properties of sodium montmorillonite suspensions
    Ramos-Tejada, MM
    de Vicente, J
    Ontiveros, A
    Durán, JDG
    JOURNAL OF RHEOLOGY, 2001, 45 (05) : 1159 - 1172
  • [49] Effect of humic matter on metal adsorption onto clay materials
    Lippold, H.
    Lippmann-Pipke, J.
    GEOCHIMICA ET COSMOCHIMICA ACTA, 2008, 72 (12) : A554 - A554
  • [50] Integrated investigations on the adsorption mechanisms of fulvic and humic acids on three clay minerals
    Zhang, Lichao
    Luo, Lei
    Zhang, Shuzhen
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2012, 406 : 84 - 90