Stereoselective Total Synthesis of Decytospolides A and B Starting from D-Mannitol

被引：4

作者：

Srilatha, Malampati ^{[1
]}

Das, Biswanath ^{[1
]}

机构：

[1] CSIR Indian Inst Chem Technol, Nat Prod Chem Div, Hyderabad 500007, Andhra Pradesh, India

来源：

HELVETICA CHIMICA ACTA | 2015年 / 98卷 / 02期

关键词：

D O I：

10.1002/hlca.201400200

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The stereoselective total synthesis of decytospolides A and B, two naturally occurring pyran derivatives, has been achieved using D-mannitol as the starting material. The intramolecular oxa-Michael reaction has been employed to construct the tetrahydropyran ring of the molecules and Weinreb amide formation to generate their side chain with a keto function.

引用

页码：267 / 272

页数：6

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