Stereoselective Total Synthesis of Decytospolides A and B Starting from D-Mannitol

被引：4
|
作者：
Srilatha, Malampati [1 ]
Das, Biswanath [1 ]
机构：
[1] CSIR Indian Inst Chem Technol, Nat Prod Chem Div, Hyderabad 500007, Andhra Pradesh, India
来源：
HELVETICA CHIMICA ACTA | 2015年 / 98卷 / 02期
关键词：
D O I：
10.1002/hlca.201400200
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The stereoselective total synthesis of decytospolides A and B, two naturally occurring pyran derivatives, has been achieved using D-mannitol as the starting material. The intramolecular oxa-Michael reaction has been employed to construct the tetrahydropyran ring of the molecules and Weinreb amide formation to generate their side chain with a keto function.
引用
收藏
页码：267 / 272
页数：6
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