Synergetic effect between sulfurized Mo/γ-Al2O3 and Ni/γ-Al2O3 catalysts in hydrodenitrogenation of quinoline

被引：5

作者：

Liu, Lihua ^{[1
]}

Liu, Bin ^{[1
]}

Chai, Yongming ^{[1
]}

Liu, Yunqi ^{[1
]}

Liu, Chenguang ^{[1
]}

机构：

[1] China Univ Petr E China, CNPC, Key Lab Catalysis, State Key Lab Heavy Oil Proc, Qingdao 266555, Shandong, Peoples R China

来源：

JOURNAL OF NATURAL GAS CHEMISTRY | 2011年 / 20卷 / 02期

关键词：

hydrogen spillover; synergetic effect; hydrodenitrogenation; NiMo catalyst; HYDROGEN SPILLOVER; HYDRODESULFURIZATION; CO; SYNERGISM; HDS;

D O I：

10.1016/S1003-9953(10)60177-6

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An evidence for the synergetic effect between the stacked bed of Mo/gamma-Al2O3 and Ni/gamma-Al2O3 in the hydrodenitrogenation (HDN) reaction of quinoline has been provided in this paper. The synergism factor decreases when the reaction temperature increases (280-340 degrees C). The synergetic effect leads to improve the hydrogenation activity for the stacked bed compared with the single Mo/gamma-Al2O3 bed, which may be attributed to the generation of hydrogen spillover on the Ni/gamma-Al2O3 catalyst.

引用

页码：214 / 217

页数：4

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