Rayleigh-Schrodinger perturbation theory for resonance tunneling

被引:4
|
作者
Fernandez, FM
机构
[1] CEQUINOR, Facultad de Ciencias Exactas, Universidad Nacional de la Plata, 1900 La Plata
来源
JOURNAL OF CHEMICAL PHYSICS | 1996年 / 105卷 / 23期
关键词
D O I
10.1063/1.472971
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We calculate accurate tunnel resonances by means of-standard Rayleigh-Schrodinger perturbation theory, exactly as if they were ordinary bound states. We choose one-dimensional barriers with a single maximum to test the convergence properties of the perturbation series. The method consists of an expansion of the potential-energy function about its maximum and a dilatation of the coordinate by means of a complex scaling parameter completely determined by the curvature of the barrier. (C) 1996 American Institute of Physics.
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页码:10444 / 10448
页数:5
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