Carbon Dioxide Carbonates in the Earth's Mantle: Implications to the Deep Carbon Cycle

被引：24

作者：

Yoo, Choong-Shik ^{[1
,2
]}

Sengupta, Amartya ^{[1
,2
]}

Kim, Minseob ^{[1
,2
]}

机构：

[1] Washington State Univ, Dept Chem, Pullman, WA 99164 USA

[2] Washington State Univ, Inst Shock Phys, Pullman, WA 99164 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 47期

基金：

美国国家科学基金会;

关键词：

amorphization; carbon dioxide; deep carbon cycle; extended CO2 carbonates; pressure-induced ionization; HIGH-PRESSURE;

D O I：

10.1002/anie.201104689

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Under pressure: An increase in the ionic character in C-O bonds at high pressures and temperatures is shown by the chemical/phase transformation diagram of CO2 (see picture). The presence of carbonate carbon dioxide (i-CO2) near the Earth′s core-mantle boundary condition provides insights into both the deep carbon cycle and the transport of atmospheric CO2 to anhydrous silicates in the mantle and iron core. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11219 / 11222

页数：4

共 50 条

[41] The synthesis of organic carbonates from carbon dioxide
Sakakura, Toshiyasu
Kohno, Kazufumi
CHEMICAL COMMUNICATIONS, 2009, (11) : 1312 - 1330
[42] Catalytic Transformation of Carbon Dioxide to Organic Carbonates
Kohno, Kazufumi
Sakakura, Toshiyasu
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2009, 67 (09) : 921 - 933
[43] The Effects of Carbon Dioxide Removal on the Carbon Cycle
Keller, David P.
Lenton, Andrew
Littleton, Emma W.
Oschlies, Andreas
Scott, Vivian
Vaughan, Naomi E.
CURRENT CLIMATE CHANGE REPORTS, 2018, 4 (03): : 250 - 265
[44] The Effects of Carbon Dioxide Removal on the Carbon Cycle
David P. Keller
Andrew Lenton
Emma W. Littleton
Andreas Oschlies
Vivian Scott
Naomi E. Vaughan
Current Climate Change Reports, 2018, 4 : 250 - 265
[45] Redox freezing and melting in the Earth’s deep mantle resulting from carbon–iron redox coupling
Arno Rohrbach
Max W. Schmidt
Nature, 2011, 472 : 209 - 212
[46] Determination of carbon dioxide in carbonates by diminished pressure
Zinn, JB
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1917, 39 : 270 - 270
[47] Carbon dioxide storage as mineral carbonates.
Fauth, DJ
Goldberg, PM
Knoer, JP
Soong, Y
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 220 : U395 - U395
[48] Detection of carbon dioxide in the analysis of carbonates or oxalates
Stafford, OF
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1918, 40 : 622 - 622
[49] DETERMINATION OF CARBONATES BY INFRARED MEASUREMENT OF CARBON DIOXIDE
POBINER, H
ANALYTICAL CHEMISTRY, 1962, 34 (07) : 878 - &
[50] Two modes of deep carbon cycling in a big mantle wedge: Differences and effects on Earth's habitability
Li S.
Wang Y.
Liu S.
Earth Science Frontiers, 2024, 31 (01) : 15 - 27

← 1 2 3 4 5 →