Study Of Nature Of Structural Defects In A Prussian Blue Type Cu0.73Mn0.77[Fe(CN)6]•zH2O Molecular Magnet

被引：0

作者：

Kumar, Amit ^{[1
]}

Yusuf, S. M. ^{[1
]}

Yakhmi, J. V. ^{[2
]}

机构：

[1] Bhabha Atom Res Ctr, Div Solid State Phys, Bombay 400085, Maharashtra, India

[2] Bhabha Atom Res Ctr, Phys Grp, Bombay 400085, Maharashtra, India

来源：

INTERNATIONAL CONFERENCE ON PHYSICS OF EMERGING FUNCTIONAL MATERIALS (PEFM-2010) | 2010年 / 1313卷

关键词：

Prussian blue type molecular magnets; Structural defects; Reverse Monte Carlo simulations;

D O I：

暂无

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

We have determined crystal structure and nature of structural defects in the Cu0.73Mn0.77[Fe(CN)(6)]center dot zH(2)O molecular magnetic compound by employing the Rietveld refinement and reverse Monte Carlo (RMC) simulation techniques on the neutron scattering data. It crystallizes in a face centred cubic structure (Space group: Fm3m). The analysis of the pair-correlation functions for the oxygen atoms of the coordinated and non-coordinated water molecules reveals a correlated local ordering of water molecules at and around the empty Fe(CN)(6) sites in this compound.

引用

页码：218 / +

页数：2

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