Hexagonal NiO nanosheets on Ni-foam as an electrocatalyst for high-performance water splitting application

被引:11
|
作者
Mishra, Rajneesh Kumar [1 ]
Kumar, Vipin [1 ]
Choi, Gyu Jin [1 ]
Ryu, Jeong Won [1 ]
Mane, Sagar M. [2 ]
Shin, Jae Cheol [2 ]
Gwag, Jin Seog [1 ]
机构
[1] Yeungnam Univ, Dept Phys, Gyongsan 38541, Gyeongbuk, South Korea
[2] Dongguk Univ Seoul, Div Elect & Elect Engn, Seoul 04620, South Korea
关键词
Hexagonal NiO nanosheets; Hydrogen evolution reaction; Stability; Water splitting; Oxygen evolution reaction; NICKEL-OXIDE;
D O I
10.1016/j.matlet.2022.132740
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This study illustrates the catalytic hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) activities of the hexagonal NiO nanosheets on Ni-foam. The NiO electrocatalyst demonstrates the low over-potentials of 83 mV/380 mV and low Tafel slopes of 209 mV dec-(1)/299 mV dec(-1) during HER/OER, respectively. It also reveals excellent stability, showing a slight change in overpotentials of 116 mV and 430 mV during HER/OER after 2000 CV cycles. Electrochemical impedance spectroscopy spectra show the series resistance of 0.83 omega/1.04 omega and charge-transfer resistance of 1.63 omega/4.70 omega during HER/OER after 2000 CV cycles.
引用
收藏
页数:5
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