cis-Dichlorobis(2,2′-biquinoline)iridium(III) hexafluorophosphate

被引：5
|
作者：
Yoshikawa, N [1 ]
Sakamoto, J
Kanehisa, N
Kai, Y
Matsumura-Inoue, T
Takashima, H
Tsukahara, K
机构：
[1] Nara Womens Univ, Fac Sci, Dept Chem, Nara 6308506, Japan
[2] Nara Univ Educ, Dept Chem, Nara 6308528, Japan
[3] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Osaka 5650871, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2003年 / 59卷
关键词：
D O I：
10.1107/S1600536803014235
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of the title compound, [IrCl2(bqn)(2)]PF6, (bqn is 2,2'-biquinoline, C18H12N2), contains a monomeric [IrCl2(bqn)(2)](+) cation and a hexafluorophosphate anion. The iridium(III) ion is coordinated by four N atoms from two bqn ligands [mean Ir-N distance 2.065 (5) Angstrom] and two Cl atoms [Ir-Cl=2.342 (2) and 2.353 (2) Angstrom], forming a distorted octahedral environment. Each 2,2'-biquinoline ligand is planar, the mean deviations from the least-squares planes being 0.2431 (6) and 0.1665 (6) Angstrom.
引用
收藏
页码：M551 / M552
页数：2
相关论文
共 50 条
  • [21] AQUATION OF CIS-DICHLOROBIS(ETHYLENEDIAMINE)COBALT(III) IN MIXED AQUEOUS SOLVENTS
    BURGESS, J
    JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (16): : 2703 - &
  • [22] THE SZILARD-CHALMERS REACTION IN CIS-DICHLOROBIS AND TRANS-DICHLOROBIS-(ETHYLENEDIAMINE)-COBALT(III) NITRATE
    RAUSCHER, HE
    SUTIN, N
    MILLER, JM
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1960, 12 (3-4): : 378 - 379
  • [23] cis-Dichlorobis(2,2′-diamino-4,4′-bi-1,3-thiazole)manganese(II) methanol solvate
    Wu, Zhi-Yong
    Zhang, Jie
    Huang, Yong
    Li, Yan-Tuan
    Sun, Wei
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M1232 - M1234
  • [24] (4,4′-dimethyl-2,2′-bipyridine)chloro-(2,2′:6′,2"-terpyridine)-iridium(III) hexafluorophosphate
    Yoshikawa, N
    Sakamoto, J
    Kanehisa, N
    Kai, Y
    Matsumura-Inoue, T
    Takashima, H
    Tsukahara, K
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : M830 - M832
  • [25] (2,2'-bipyridine) chloro(4'-tolyl-2,2': 6',2''-terpyridine) iridium(III) bis(hexafluorophosphate) acetonitrile disolvate
    Yutaka, T
    Obara, S
    Haga, M
    Yokoyama, Y
    Sakai, K
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M1357 - M1359
  • [26] DICHLOROBIS (2,2'-BIPYRIDYL)COBALT(III) CHLORIDE
    DOLLIMOR.LS
    GILLARD, RD
    CHEMISTRY & INDUSTRY, 1973, (16) : 377 - 377
  • [27] cis-Dichlorobis(tri-2-furylphosphine)palladium(II) dichloromethane hemisolvate
    Meijboom, Reinout
    Muller, Alfred
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M2642 - M2644
  • [28] A polymorph of cis-dichlorobis(phenanthroline-κ2N,N′)manganese(II)
    Pan, TT
    Xu, DJ
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M740 - M742
  • [29] KINETICS OF AQUATION OF CIS-DICHLOROBIS(1,2-DIAMINOBENZENE)CHROMIUM(III) CATION
    CHANG, JC
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1976, 38 (07): : 1390 - 1391
  • [30] BASE HYDROLYSIS OF CIS-DICHLOROBIS (1,10-PHENANTHROLINE) COBALT(III)CHLORIDE
    CAMPBELL, SE
    BURKE, JA
    TEXAS JOURNAL OF SCIENCE, 1975, 26 (3-4): : 553 - 558
12345