Calibration transfer in multivariate methods.

被引:28
|
作者
Honorato, Fernanda Araujo [1 ]
Neto, Benicio de Barros
Martins, Marcelo Nascimento
Galvao, Roberto Kawakami Harrop
Pimentel, Maria Fernanda
机构
[1] Univ Fed Pernambuco, Dept Quim Fundamental, BR-50670901 Recife, PE, Brazil
[2] Inst Tecnol Aeronaut, Div Engn Elect, BR-12228900 Sao Jose Dos Campos, Brazil
[3] Univ Fed Pernambuco, Dept Engn Quim, BR-50740521 Recife, PE, Brazil
来源
QUIMICA NOVA | 2007年 / 30卷 / 05期
关键词
calibration transfer; NIR; standardization;
D O I
10.1590/S0100-40422007000500044
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Calibration transfer has received considerable attention in the recent literature. Several standardization methods have been proposed for transferring calibration models between equipments. The goal of this paper is to present a general revision of calibration transfer techniques. Basic concepts will be reviewed. as well as the main advantages and drawbacks of each technique. A case study based on a set of 80 NIR spectra of maize samples recorded on two different instruments is used to illustrate the main calibration transfer techniques (direct standardization, piecewise direct standardization. orthogonal signal Correction and robust variable selection).
引用
收藏
页码:1301 / 1312
页数:12
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