Synthesis and characterization of new inorganic-organic hybrid materials of the Cu(II)-phenanthroline-oxovanadate system

被引：2
|
作者：
Schwendt, P [1 ]
Joniaková, D
Gyepes, R
Micka, Z
机构：
[1] Comenius Univ, Fac Nat Sci, Dept Inorgan Chem, SK-84215 Bratislava, Slovakia
[2] Charles Univ Prague, Fac Nat Sci, Dept Inorgan Chem, CZ-12800 Prague, Czech Republic
来源：
SOLID STATE CHEMISTRY V | 2003年 / 90-91卷
关键词：
copper(II) complexes; polyoxovanadates; infrared spectra;
D O I：
10.4028/www.scientific.net/SSP.90-91.423
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Reactions in the CuSO4-phen-KVO3-H2O (KOH, ethanol) systems yielded two new compounds [Cu-2(phen)(2)V4O12] . 5H(2)O, 1, and [Cu(phen)(3)](VO3)(2) . 20H(2)O, 2 (phen = 1,10-, phenanthroline). A structure, containing a V4O124- cluster to which Cu(phen) fragments are attached through Cu-O bonds, was proposed for 1, while 2 is probably constructed from discrete [Cu(phen)(3)](2+) ions and polymeric (VO3)(n)(n-) chains. Compounds 1 and 2 represent new types in the group of Cu(II)-1,10-phenathroline-oxovanadate compounds.
引用
收藏
页码：423 / 426
页数：4
相关论文
共 50 条
  • [31] Perfluoroaryl substituted inorganic-organic hybrid materials
    Roscher, C
    Popall, M
    BETTER CERAMICS THROUGH CHEMISTRY VII: ORGANIC/INORGANIC HYBRID MATERIALS, 1996, 435 : 547 - 552
  • [32] Characteristics of colored inorganic-organic hybrid materials
    Wojtach, K.
    Laczka, M.
    Cholewa-Kowalska, K.
    Olejniczak, Z.
    Sokolowska, J.
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2007, 353 (18-21) : 2099 - 2103
  • [33] Progress in research of inorganic-organic hybrid materials
    Liu, Zhen
    Wu, Qingyin
    Zhong, Fangrui
    Shiyou Huagong/Petrochemical Technology, 2008, 37 (07): : 649 - 655
  • [34] Inorganic-organic hybrid materials and their adsorbent properties
    Asgar Kayan
    Advanced Composites and Hybrid Materials, 2019, 2 : 34 - 45
  • [35] Synthesis of metal alkoxide precursors to hybrid inorganic-organic composite materials
    Kennedy, Steve
    Syrigos, Jonathan
    Bates, Susan E.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
  • [36] Synthesis of inorganic-organic hybrid materials from TEOS, TBT and PDMS
    Téllez, L
    Rubio, J
    Rubio, F
    Morales, E
    Oteo, JL
    JOURNAL OF MATERIALS SCIENCE, 2003, 38 (08) : 1773 - 1780
  • [37] Inorganic-organic hybrid materials and their adsorbent properties
    Kayan, Asgar
    ADVANCED COMPOSITES AND HYBRID MATERIALS, 2019, 2 (01) : 34 - 45
  • [38] A new polymeric intermediate for the synthesis of hybrid inorganic-organic polymers
    Stone, David A.
    Allcock, Harry R.
    MACROMOLECULES, 2006, 39 (15) : 4935 - 4937
  • [39] Synthesis of inorganic-organic hybrid materials from TEOS, TBT and PDMS
    L. Téllez
    J. Rubio
    F. Rubio
    E. Morales
    J. L. Oteo
    Journal of Materials Science, 2003, 38 : 1773 - 1780
  • [40] Synthesis and Characterization of Novel Inorganic-Organic Hybrid Ru(II) Complexes and Their Application in Selective Hydrogenation
    Warad, Ismail
    Al-Othman, Zeid
    Al-Resayes, Saud
    Al-Deyab, Salem S.
    Kenawy, El-Refaie
    MOLECULES, 2010, 15 (02) : 1028 - 1040
12345