Synthesis and characterization of new inorganic-organic hybrid materials of the Cu(II)-phenanthroline-oxovanadate system

被引：2
|
作者：
Schwendt, P [1 ]
Joniaková, D
Gyepes, R
Micka, Z
机构：
[1] Comenius Univ, Fac Nat Sci, Dept Inorgan Chem, SK-84215 Bratislava, Slovakia
[2] Charles Univ Prague, Fac Nat Sci, Dept Inorgan Chem, CZ-12800 Prague, Czech Republic
来源：
SOLID STATE CHEMISTRY V | 2003年 / 90-91卷
关键词：
copper(II) complexes; polyoxovanadates; infrared spectra;
D O I：
10.4028/www.scientific.net/SSP.90-91.423
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Reactions in the CuSO4-phen-KVO3-H2O (KOH, ethanol) systems yielded two new compounds [Cu-2(phen)(2)V4O12] . 5H(2)O, 1, and [Cu(phen)(3)](VO3)(2) . 20H(2)O, 2 (phen = 1,10-, phenanthroline). A structure, containing a V4O124- cluster to which Cu(phen) fragments are attached through Cu-O bonds, was proposed for 1, while 2 is probably constructed from discrete [Cu(phen)(3)](2+) ions and polymeric (VO3)(n)(n-) chains. Compounds 1 and 2 represent new types in the group of Cu(II)-1,10-phenathroline-oxovanadate compounds.
引用
收藏
页码：423 / 426
页数：4
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