Planar Macrocyclic Fluoropentamers as Supramolecular Organogelators

被引：57

作者：

Ren, Changliang ^{[1
,2
]}

Xu, Shengyu ^{[1
,2
]}

Xu, Jun ^{[3
]}

Chen, Hongyu ^{[3
]}

Zeng, Huaqiang ^{[1
,2
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

[2] Natl Univ Singapore, NUS MedChem Program, Off Life Sci, Singapore 117543, Singapore

[3] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 15期

关键词：

GEL-PHASE MATERIALS; TRIGGERED HYDROGELATOR; ETHYNYLENE MACROCYCLE; AROMATIC OLIGOAMIDES; RECOGNITION; CHIRALITY; VESICLES; GELATORS; GELATION;

D O I：

10.1021/ol201361f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Despite their great diversities, 2D-shaped macrocycles that can serve as the organogelators have been surprisingly rare; two planar macrocyclic fluoropentamers designed by us were highly able to gelate organic solvents, largely derived from their strong tendency to form 1D stacked fibrillar structures stabilized by both interplanar H-bonds and pi-pi stacking forces.

引用

页码：3840 / 3843

页数：4

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