Planar Macrocyclic Fluoropentamers as Supramolecular Organogelators

被引:57
|
作者
Ren, Changliang [1 ,2 ]
Xu, Shengyu [1 ,2 ]
Xu, Jun [3 ]
Chen, Hongyu [3 ]
Zeng, Huaqiang [1 ,2 ]
机构
[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
[2] Natl Univ Singapore, NUS MedChem Program, Off Life Sci, Singapore 117543, Singapore
[3] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore
关键词
GEL-PHASE MATERIALS; TRIGGERED HYDROGELATOR; ETHYNYLENE MACROCYCLE; AROMATIC OLIGOAMIDES; RECOGNITION; CHIRALITY; VESICLES; GELATORS; GELATION;
D O I
10.1021/ol201361f
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Despite their great diversities, 2D-shaped macrocycles that can serve as the organogelators have been surprisingly rare; two planar macrocyclic fluoropentamers designed by us were highly able to gelate organic solvents, largely derived from their strong tendency to form 1D stacked fibrillar structures stabilized by both interplanar H-bonds and pi-pi stacking forces.
引用
收藏
页码:3840 / 3843
页数:4
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