Highly efficient and diastereoselective synthesis of 1,3-oxazolidines featuring a palladium-catalyzed cyclization reaction of 2-butene-1,4-diol derivatives and imines

被引：14

作者：

Chen, Dongxu ^{[1
]}

Chen, Xiaoyi ^{[1
]}

Du, Taiping ^{[1
]}

Kong, Lichun ^{[1
]}

Zhen, Renwei ^{[1
]}

Zhen, Shaocheng ^{[1
]}

Wen, Yihang ^{[2
]}

Zhu, Gangguo ^{[1
,2
]}

机构：

[1] Zhejiang Normal Univ, Dept Chem, Jinhua 321004, Peoples R China

[2] Zhejiang Normal Univ, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Peoples R China

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 39期

基金：

中国国家自然科学基金;

关键词：

ASYMMETRIC-SYNTHESIS; ALLYLIC SUBSTITUTION; 3+2 CYCLOADDITION; LIGANDS; OXAZOLIDINES; AMINOHYDROXYLATION; EQUIVALENT; OLEFINS;

D O I：

10.1016/j.tetlet.2010.07.087

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A palladium-catalyzed protocol for effective synthesis of 1,3-oxazolidines has been reported. This method is featured by the high diastereoselectivity (dr up to >98/2) and using the readily available 2-butene-1,4-diol derivatives and imines as substrates. (c) 2010 Elsevier Ltd. All rights reserved.

引用

页码：5131 / 5133

页数：3

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