Highly efficient and diastereoselective synthesis of 1,3-oxazolidines featuring a palladium-catalyzed cyclization reaction of 2-butene-1,4-diol derivatives and imines

被引：14
|
作者：
Chen, Dongxu [1 ]
Chen, Xiaoyi [1 ]
Du, Taiping [1 ]
Kong, Lichun [1 ]
Zhen, Renwei [1 ]
Zhen, Shaocheng [1 ]
Wen, Yihang [2 ]
Zhu, Gangguo [1 ,2 ]
机构：
[1] Zhejiang Normal Univ, Dept Chem, Jinhua 321004, Peoples R China
[2] Zhejiang Normal Univ, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Peoples R China
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 39期
基金：
中国国家自然科学基金;
关键词：
ASYMMETRIC-SYNTHESIS; ALLYLIC SUBSTITUTION; 3+2 CYCLOADDITION; LIGANDS; OXAZOLIDINES; AMINOHYDROXYLATION; EQUIVALENT; OLEFINS;
D O I：
10.1016/j.tetlet.2010.07.087
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A palladium-catalyzed protocol for effective synthesis of 1,3-oxazolidines has been reported. This method is featured by the high diastereoselectivity (dr up to >98/2) and using the readily available 2-butene-1,4-diol derivatives and imines as substrates. (c) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5131 / 5133
页数：3
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