Scandia-doped tungsten bodies for Sc-type cathodes

被引:35
|
作者
Wang, JS [1 ]
Wang, YM [1 ]
Tao, SW [1 ]
Li, HY [1 ]
Yang, JC [1 ]
Zhou, ML [1 ]
机构
[1] Beijing Polytech Univ, Minist Educ, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Beijing 100022, Peoples R China
关键词
scandate-type cathodes; surface behavior; electron emission properties; scandium oxides; ion bombardment; microstructure; Ba dispenser cathodes; impregnated cathodes;
D O I
10.1016/S0169-4332(03)00322-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We systematically investigated scandium oxide-doped (and with small amount of rhenium-doped) tungsten bodies for Scandate-type cathodes. Homogeneous microstructure and uniform distribution of scandia were found in these bodies. Sub-micron granular porous bodies with greatly uniformly dispersed scandia are obtained by sintering Sc2O3 and Re doped tungsten powder. Such bodies are thought to be beneficial for emission uniformity. For Scandate-type cathodes with such bodies, a slight decrease of scandia was observed by "in situ" AES analysis after ion sputtering, but it recovers completely on reheating. It is assumed that film-like Sc2O3 coating over tungsten grains but leaving porous areas for diffusion of barium to the surface leads to good emission properties and high resistance to ion bombardment. Reprocucibility has been proved for the body manufactering process. This offers the possibility of improving the performance of these cathodes in applications such as CRT's. (C) 2003 Published by Elsevier Science B.V.
引用
收藏
页码:38 / 48
页数:11
相关论文
共 50 条
  • [21] Defects and phase transitions in yttria- and scandia-doped zirconia
    Weller, M
    Khelfaoui, F
    Kilo, M
    Taylor, MA
    Argirusis, C
    Borchardt, G
    SOLID STATE IONICS, 2004, 175 (1-4) : 329 - 333
  • [22] Processing and Properties of Scandia-doped Zirconia Electrolyte for Intermediate Temperature SOFC
    Singh, R. N.
    Chavan, S. V.
    SOLID OXIDE FUEL CELLS 10 (SOFC-X), PTS 1 AND 2, 2007, 7 (01): : 2207 - 2212
  • [23] Properties of Scandia-doped Zirconia Synthesized by the Polymeric Precursor and the Polyacrylamide Techniques
    Muccillo, R.
    Costa, G. C. C.
    IONIC AND MIXED CONDUCTING CERAMICS 7, 2010, 28 (11): : 315 - 323
  • [24] A novel approach to synthesis of scandia-doped tungsten nano-particles for high-current-density cathode applications
    Barik, R. K.
    Bera, A.
    Tanwar, A. K.
    Baek, I. K.
    Min, S. H.
    Kwon, O. J.
    Lee, W. S.
    Park, G-S
    INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2013, 38 : 60 - 66
  • [25] Preparation and characterisation of scandia doped dispenser cathodes
    Wang, Jinshu
    Wang, Xi
    Liu, Wei
    Cui, Yuntao
    Wang, Yiman
    Zhou, Meiling
    INTERNATIONAL JOURNAL OF NANOTECHNOLOGY, 2013, 10 (1-2) : 108 - 118
  • [26] Simplified SC-type receptacles for ONU
    Nagase, R
    Kato, K
    Iwano, S
    Mitachi, S
    NTT REVIEW, 1997, 9 (02): : 58 - 62
  • [27] Scandia-doped zirconia for the electrochemical detection of hazardous dihydroxybenzene (DHB) isomers in water
    Ferlazzo, Angelo
    Gulino, Antonino
    Neri, Giovanni
    ENVIRONMENTAL SCIENCE-ADVANCES, 2024, 3 (10): : 1392 - 1399
  • [28] Structure and conductivity of yttria and scandia-doped zirconia crystals grown by skull melting
    Borik, Mihail A.
    Bredikhin, Sergey I.
    Bublik, Vladimir T.
    Kulebyakin, Aleksej V.
    Kuritsyna, Irina E.
    Lomonova, Elena E.
    Milovich, Philipp O.
    Myzina, Valentina A.
    Osiko, Vyacheslav V.
    Ryabochkina, Polina A.
    Tabachkova, Nataliya Y.
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2017, 100 (12) : 5536 - 5547
  • [29] Synthesis of scandia-doped zirconia(ScSZ) ceramic powder and thermal dynamics of the precursor
    Liu, Ji-Bo
    Bao, Xin-Jun
    Chinese Rare Earths, 2014, 35 (03) : 45 - 48
  • [30] Structure and conductivity of yttria and scandia-doped zirconia crystals grown by skull melting
    Milovich, Philipp O. (philippmilovich@gmail.com), 1600, Blackwell Publishing Inc., Postfach 10 11 61, 69451 Weinheim, Boschstrabe 12, 69469 Weinheim, Deutschland, 69469, Germany (100):