Reactions of [ReX5(NO)]2- with triphenylstibine.: Spectroscopic investigations of [ReX2(NO)(SbPh3)3], X-ray structures of [ReCl2(NO)(SbPh3)3] and [ReBr2Cl(SbPh3)3] and DFT calculations for [ReCl2(NO)(SbPh3)3]

被引：5

作者：

Machura, B

Kruszynski, R

Jaworska, M

机构：

[1] Silesian Univ, Inst Chem, Dept Inorgan & Radiat Chem, PL-40006 Katowice, Poland

[2] Tech Univ Lodz, Inst Gen & Ecol Chem, Dept Xray Crystallog & Crytal Chem, PL-90924 Lodz, Poland

[3] Silesian Univ, Inst Chem, Dept Theoret Chem, PL-40006 Katowice, Poland

来源：

POLYHEDRON | 2005年 / 24卷 / 03期

关键词：

rrhenium; stibine; nitrosyl complexes; X-ray structure; DFT calculations;

D O I：

10.1016/j.poly.2004.11.028

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of [NBu4](2)[ReX5(NO)] (X = Cl, Br) with triphenylstibine have been examined and three new rhenium complexes [ReCl2(NO)(SbPh3)(3)] (1), [ReBr2(NO)(SbPh3)(3)] (2) and [ReBr2Cl(SbPh3)(3)] (3) - have been obtained. The last one has been isolated in a low yield during slow recrystallization of the complex 2 from a mixture of chloroform and ethanol. The stibine rhenium nitrosyls have been characterized by IR and UV-vis spectroscopy. The X-ray structures of and 3 have been determined. The geometric parameters of 1 have been examined using the density functional theory (DFT) method. (C) 2005 Elsevier Ltd. All rights reserved.

引用

页码：419 / 426

页数：8

共 50 条

[31] SYNTHESIS AND PROPERTIES OF PENTACHLORO(LIGAND)IRIDATE(IV) ANIONS [IRLCL5]-(L = PYRIDINE, PPH3, ASPH3, SBPH3, SME2, SPH2, OR SEME2)
CIPRIANO, RA
LEVASON, W
MOULD, RAS
PLETCHER, D
POWELL, NA
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (10): : 2677 - 2679
[32] Antimony-Carbon bond activation in a Pt(II) complex: The crystal structure of [Pt(9S3)(SbPh3)(Ph)](PF6)•CH3NO2
Grant, Gregory J.
Benefield, Desiree A.
VanDerveer, Donald G.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2010, 695 (04) : 634 - 636
[33] REACTIONS OF THE 7-CO-ORDINATE COMPLEXES [ML2(CO)3(NCME)2] AND [ML2(CO)3(NCME)L] (M = MO OR W - L = PPH3, ASPH3 OR SBPH3) WITH DITHIOCARBAMATE LIGANDS
BAKER, PK
FRASER, SG
KENDRICK, DA
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (01): : 131 - 136
[34] Ligand substitution in the osmium-antimony rings Os3(μ-SbPh2)2 (CO)10 and Os3(μ-SbPh2)3(Cl)(CO)9
Li, Ying-Zhou
Ganguly, Rakesh
Leong, Weng Kee
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2016, 820 : 46 - 54
[35] Ruthenium hydrides bearing SbPh3 and AsPh3 ligands:: characterization of the bis(dihydrogen) complexes [Cp*Ru(H2)2(EPh3)]+ (Cp* = C5Me5; E = Sb, As)
Aneetha, H
Tenorio, MJ
Puerta, MC
Valerga, P
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 663 (1-2) : 151 - 157
[36] SYNTHESIS, AND F-19 NMR AND X-RAY STRUCTURAL STUDIES OF TRIOSMIUM CLUSTERS (MU-H)OS3(CO)10L[ON(CF3)2](L=PPH3, ASPH3 AND SBPH3)
ANG, HG
KOH, CH
KOH, LL
KWIK, WL
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 452 (1-2) : 181 - 184
[37] Carbonyl Displacement Reaction in Diiron Propane-Dithiolate Complex by Triphenylstibine: Crystal Structure of [Fe2(CO)6-n(SbPh3)n(μ-S2C3H6)] (n=1 and 2)
Islam, Shafikul
Hossain, Md. Imran
Karim, Md. Manzurul
Bhoumik, Nikhil C.
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2022, 52 (01) : 17 - 24
[38] PREPARATION, CHARACTERIZATION AND A KINETIC-STUDY OF TRANS-[RU(NH3)4L(H2O)](PF6)2 [L = PPH3, ASPH3, OR SBPH3]
DEREZENDE, JM
FRANCO, DW
TRANSITION METAL CHEMISTRY, 1987, 12 (03) : 267 - 270
[39] A high-yield synthetic approach to trans-[Ir(ER3)2(CO)X] (ER3 = PMe3, PEt3, PPhMe2, PPh2Me, P(OMe)3, AsMe3, AsEt3, AsPh3, SbPh3; X = Cl, Br)
Field, LD
Lawrenz, ET
Ward, AJ
POLYHEDRON, 1999, 18 (23) : 3031 - 3034
[40] Carbonyl Displacement Reaction in Diiron Propane-Dithiolate Complex by Triphenylstibine: Crystal Structure of [Fe2(CO)6-n(SbPh3)n(μ-S2C3H6)] (n = 1 and 2)
Shafikul Islam
Md. Imran Hossain
Md. Manzurul Karim
Nikhil C. Bhoumik
Journal of Chemical Crystallography, 2022, 52 : 17 - 24

← 1 2 3 4 5 →