Infinite-Dilution Activity Coefficients of Volatile Organic Compounds in Cyclic Olefin Copolymers

被引：0

作者：

Alessi, P. ^{[1
]}

Cortesi, A. ^{[1
]}

Kikic, I. ^{[1
]}

Solinas, D. ^{[1
]}

De Zordi, N. ^{[2
]}

Moneghini, M. ^{[2
]}

机构：

[1] Univ Trieste, Dept Ind Engn & Informat Technol, I-34127 Trieste, Italy

[2] Univ Trieste, Dept Chem & Pharmaceut Sci, I-34127 Trieste, Italy

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2011年 / 56卷 / 04期

关键词：

INVERSE GAS-CHROMATOGRAPHY; SOLUTE DESCRIPTORS; PREDICTION; PARAMETERS; DIFFUSION; ABRAHAM; SYSTEMS; SETS;

D O I：

10.1021/je101120j

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Infinite-dilution activity coefficients for nine classes of volatile organic compounds (paraffins, olefins, cycloparaffins, aromatics, ketones, nitriles, alcohols, esters, and chlorocompounds) in a series of four cyclic olefin copolymers were determined using an inverse gas chromatography technique with a packed column. Abraham's equation of solvation was used for the evaluation of the different types of interactions between the solvents and polymers. The results are compared with the activity coefficients at infinite dilution obtained for other polymers of similar use.

引用

页码：1255 / 1260

页数：6

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