In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes

被引：7
|
作者：
Liautard, Virginie [1 ]
Delgado, Marine [1 ,2 ]
Colin, Boris [2 ]
Chabaud, Laurent [1 ]
Michaud, Guillaume [2 ]
Pucheault, Mathieu [1 ]
机构：
[1] Univ Bordeaux, ISM, Bordeaux INP, CNRS,UMR 5255, F-33400 Talence, France
[2] ZAC Bois Plaisance, BOSTIK, Smart Technol Ctr, 101 Rue Champ Cailloux, F-60280 Venette, France
来源：
CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 13期
关键词：
MOLECULAR ADDITION-COMPOUNDS; HOMOLYTIC REACTIONS; LIGATED BORANES; TRIETHYLBORANE; CYCLIZATION; REAGENT;
D O I：
10.1039/d1cc06390a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Atom transfer radical addition of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes. Thanks to a slow hydroboration step, the overall carbohalogenation process leads to good isolated yields.
引用
收藏
页码：2124 / 2127
页数：4
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