The synthesis of spirobitetraline phosphoramidite ligands and their application in rhodium-catalyzed asymmetric hydrogenation

被引：22

作者：

Huo, Xiang-Hong

Xie, Jian-Hua

Wang, Qiu-Shi

Zhou, Qi-Lin ^{[1
]}

机构：

[1] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China

[2] Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2007年 / 349卷 / 16期

关键词：

asymmetric catalysis; hydrogenation; monophosphoramidite; rhodium; spirobitetraline;

D O I：

10.1002/adsc.200700109

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A racemic 1,1'-spirobitetralin-8,8'-diol (SBITOL) was conveniently synthesized from 3-methoxybenzaldehyde in 26 % yield over 9 steps and resolved via its bis-(S)-camphorsulfonates. The corresponding chiral spirobitetraline monophosphoramidite ligands have been prepared and their rhodium complexes were applied in the asymmetric hydrogenation of dehydroamino esters with good to excellent enantioselectivities (up to 99.3 % ee).

引用

页码：2477 / 2484

页数：8

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