Decarbonylative Reductive Coupling of Aromatic Esters by Nickel and Palladium Catalyst

被引：5
|
作者：
Peng, Yunfei [1 ]
Isshiki, Ryota [1 ]
Muto, Kei [2 ]
Yamaguchi, Junichiro [1 ]
机构：
[1] Waseda Univ, Dept Appl Chem, Shinjuku Ku, 513 Wasedatsurumakicho, Tokyo 1620041, Japan
[2] Waseda Univ, Waseda Inst Adv Study, Shinjuku Ku, 513 Wasedatsurumakicho, Tokyo 1620041, Japan
来源：
CHEMISTRY LETTERS | 2022年 / 51卷 / 07期
关键词：
Decarbonylative reaction; Reductive coupling; Biaryls; ARYL BOND FORMATION; BIARYL COMPOUNDS; ALPHA-ARYLATION; C-O; PD; INTERCONVERSION; OLEFINATION; SILYLATION; CHEMISTRY; KETONES;
D O I：
10.1246/cl.220214
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ni or Pd-catalyzed decarbonylative reductive couplings of aromatic esters were developed. A range of (hetero)aromatic esters was applicable to these reductive homocoupling reactions. Moreover, it was found that Pd-catalysis enables a reductive decarbonylative cross-coupling between two different aromatic esters to afford a nonsymmetrical biaryls system.
引用
收藏
页码：749 / 753
页数：5
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