Novel photoactive single-walled carbon nanotube-porphyrin polymer wraps: Efficient and long-lived intracomplex charge separation

被引：192
|
作者：
Guldi, DM [1 ]
Taieb, H
Rahman, GMA
Tagmatarchis, N
Prato, M
机构：
[1] Univ Erlangen Nurnberg, Inst Chem Phys, D-91085 Erlangen, Germany
[2] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46556 USA
[3] Univ Trieste, Dipartimento Sci Farmaceut, I-34127 Trieste, Italy
来源：
ADVANCED MATERIALS | 2005年 / 17卷 / 07期
关键词：
D O I：
10.1002/adma.200400641
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel donor-acceptor nanoassemblies (see cover) are prepared using pristine single-walled carbon nanotubes (SWNTs) as electron-acceptor components in supramolecular "polymer wraps", with poly(methyl methacrylate) carrying porphyrin units (H2P) as excited-state electron donors (see Figure). In these novel donor-acceptor ensembles, SWNTs quench the photoexcited H2P chromophores, resulting in the creation of long-lived radical ion pairs.
引用
收藏
页码：871 / +
页数：6
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