Study of the Hydrothermal-Catalytic Influence on the Oil-Bearing Rocks of the Usinskoye Oil Field

被引:5
|
作者
Mukhamatdinov, Irek I. [1 ]
Lapin, Artem, V [1 ]
Mukhamatdinova, Rezeda E. [1 ]
Akhmadiyarov, Aydar A. [1 ]
Affane, Boudkhil [1 ]
Emel'yanov, Dmitriy A. [1 ]
Slavkina, Olga, V [2 ]
Vakhin, Alexey V. [1 ]
机构
[1] Kazan Volga Reg Fed Univ, Inst Geol & Petr Technol, 18 Kremlyovskaya Str, Kazan 420008, Russia
[2] LLC RITEK, 85 Lesogorskaya Str, Volgograd 400048, Russia
关键词
aquathermolysis; catalyst precursor; thermal steam treatment; iron tallate; viscosity; SARA; GC-MS; molecular mass; SEM; TG-DSC; HEAVY OIL; BIOMARKER HYDROCARBONS; VISCOSITY REDUCTION; NATURAL BITUMEN; AQUATHERMOLYSIS; STEAM; TRANSFORMATIONS; NANOPARTICLES; THERMOLYSIS; ASPHALTENE;
D O I
10.3390/catal12101268
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, a synthesis of an oil-soluble iron-based catalyst precursor was carried out and its efficiency was tested in a laboratory simulation of the aquathermolysis process at different temperatures. The rocks of the Usinskoe field from the Permian deposits of the Komi Republic, obtained by steam-gravity drainage, and the iron-based catalyst precursor, as well as the products of non-catalytic and catalytic aquathermolysis, were selected as the object of study. As a result, it was found that the content of alkanes in the samples after thermal steam treatment (TST) at 300 degrees C increased 8-fold compared to the original oil, and the content of cycloalkanes in the sample with the catalyst increased 2-fold compared to the control experience. This may indicate that not only the carbon-heteroatom bonds (C-S, N, O) but also the C-C bonds were broken. It also shows that increasing the iron tallate concentration at TST 300 degrees C leads to a decrease in the molecular mass of the oil compared to the control experiment. According to SEM, the catalyst is nanodisperse particles with a size of approximate to 60-80 nm, which are adsorbed on the rock surface, catalyst removal occurs at a small scale.
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页数:26
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