Study of native oil-bearing rocks of the Cuban basin by high resolution NMR spectroscopy

被引:1
|
作者
Rakhmatullin, Ilfat Z. [1 ]
Efimov, Sergej, V [1 ]
Kondratyeva, Ekaterina I. [1 ]
Gonzalez, Lisset Miquel [1 ]
Safiullin, Kajum R. [1 ]
Varfolomeev, Mikhail A. [1 ]
Klochkov, Alexander, V [1 ]
Klochkov, Vladimir V. [1 ]
机构
[1] Kazan Fed Univ, 18 Kremlevskaya St, Kazan 420008, Russia
关键词
13C NMR spectroscopy; Cuba oil; Rock sample; Functional group; Qualitative analysis; Quantitative composition; Aromaticity; CRUDE OILS; C-13; SAMPLES; H-1;
D O I
10.1016/j.ptlrs.2022.01.001
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Application of high resolution 13 C nuclear magnetic resonance (NMR) spectroscopy to characterize Cuba oil and oil-containing rock samples from Cuban basin was demonstrated. The chemical shifts of 13 C NMR functional groups for later determination the composition of the oil and rock samples were determined. The different contribution of the studied samples in the aliphatic and aromatic areas was determined. Molar fractions of primary, secondary, quaternary, tertiary, aromatic groups, aromaticity factor and the mean length of hydrocarbon chain length of aliphatic hydrocarbons were estimated. Comparative analysis on the quantitative level for all major hydrocarbon components, the aromaticity factor and the mean length of the hydrocarbon chain were carried out. (c) 2022 The Authors. Publishing services provided by Elsevier B.V. on behalf of KeAi Communication Co. Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/ by-nc-nd/4.0/).
引用
收藏
页码:495 / 499
页数:5
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