Study of the Surface Tensions of Binary Mixtures of Isomeric Chlorobutanes with Methyl tert-Butyl Ether

被引:10
|
作者
Montano, Diego [1 ]
Bandres, Isabel [1 ]
Ballesteros, Luz M. [1 ]
Lafuente, Carlos [1 ]
Royo, Felix M. [1 ]
机构
[1] Univ Zaragoza, Fac Ciencias, Dept Quim Organ Quim Fis, E-50009 Zaragoza, Spain
关键词
Surface tension; Isomeric chlorobutanes; Methyl tert-butyl ether; EXCESS MOLAR VOLUMES; MTBE; TEMPERATURE; VISCOSITIES; ADSORPTION; DENSITIES; INTERFACE;
D O I
10.1007/s10953-011-9717-z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the present work we report experimental surface tensions for binary mixtures of isomeric chlorobutanes with methyl tert-butyl ether from 283.15 to 303.15 K, measured with a drop volume tensiometer. From these experimental data the corresponding surface tension deviations were calculated and correlated using a Redlich-Kister type polynomial. Finally, we include the calculation of excess surface compositions for all of the mixtures from 288.15 K to 308.15 K.
引用
收藏
页码:1173 / 1186
页数:14
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