[TcCl(CS)(dppe)2]•C6H6

被引：1
|
作者：
Bryan, JC [1 ]
Burrell, AK
Kubas, GJ
机构：
[1] Oak Ridge Natl Lab, Div Chem & Analyt Sci, Oak Ridge, TN 37831 USA
[2] Massey Univ, Inst Fundamental Sci, Palmerston North, New Zealand
[3] Los Alamos Natl Lab, Los Alamos, NM 87545 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷
关键词：
D O I：
10.1107/S1600536800019486
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, chlorobis[1,2-ethanediylbis(diphenylphosphine)-P,P'](thiocarbonyl-C)technetium benzene solvate, [TcCl(C46H42P4)(CS)] . C6H6, was obtained as one of two Tc-containing products isolated from the reaction between CS2 and the electron-dfircient complex [TcCl\-th>(dppe)(2)], where dppe is 1,2-ethanediylbis(diphenylphosphine). The structure exhibits an unusually short Tc-C distance [1.819 (6) Angstrom], suggesting some multiple-bond character.
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收藏
页码：M23 / M24
页数：2
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