[TcCl(CS)(dppe)2]•C6H6

被引：1
|
作者：
Bryan, JC [1 ]
Burrell, AK
Kubas, GJ
机构：
[1] Oak Ridge Natl Lab, Div Chem & Analyt Sci, Oak Ridge, TN 37831 USA
[2] Massey Univ, Inst Fundamental Sci, Palmerston North, New Zealand
[3] Los Alamos Natl Lab, Los Alamos, NM 87545 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷
关键词：
D O I：
10.1107/S1600536800019486
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, chlorobis[1,2-ethanediylbis(diphenylphosphine)-P,P'](thiocarbonyl-C)technetium benzene solvate, [TcCl(C46H42P4)(CS)] . C6H6, was obtained as one of two Tc-containing products isolated from the reaction between CS2 and the electron-dfircient complex [TcCl\-th>(dppe)(2)], where dppe is 1,2-ethanediylbis(diphenylphosphine). The structure exhibits an unusually short Tc-C distance [1.819 (6) Angstrom], suggesting some multiple-bond character.
引用
收藏
页码：M23 / M24
页数：2
相关论文
共 50 条
  • [1] ORIENTATIONAL CORRELATION PARAMETER FOR LIQUID CS2, C6H6 AND C6F6
    BATTAGLIA, MR
    COX, TI
    MADDEN, PA
    [J]. MOLECULAR PHYSICS, 1979, 37 (05) : 1413 - 1427
  • [2] KERR EFFECT IN CS2, C6H6, AND CCL4
    MYERS, SA
    ROBINSON, EJ
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1973, 58 (08): : 3526 - 3527
  • [3] KERR EFFECT IN CS2, C6H6, AND CCL4
    MYERS, SA
    ROBINSON, EJ
    [J]. BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1971, 16 (12): : 1397 - &
  • [4] ION SURFACE COLLISIONS FOR DISTINCTION OF ISOMERIC [C6H6].+ AND [C6H6]2+ IONS
    HAYWARD, MJ
    MABUD, MA
    COOKS, RG
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (05) : 1343 - 1346
  • [5] PHOTODISSOCIATION SPECTROSCOPY OF (C6H6)(2)(+)
    OHASHI, K
    NAKAI, Y
    SHIBATA, T
    NISHI, N
    [J]. LASER CHEMISTRY, 1994, 14 (1-3) : 3 - 14
  • [6] DETERMINATION OF THE STABILITIES AND STRUCTURES OF CL-(C6H6), BR-(C6H6), I-(C6H6) CLUSTERS
    HIRAOKA, K
    MIZUSE, S
    YAMABE, S
    [J]. CHEMICAL PHYSICS LETTERS, 1988, 147 (2-3) : 174 - 178
  • [7] BENZENE (C6H6)
    YOKOGAWA, A
    [J]. JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1984, 42 (07) : 679 - 680
  • [8] Ab initio determination of the C6H6•••CS2 cluster stabilization energy
    da Silveira, NP
    Rodembusch, FS
    Pereira, FV
    Samios, D
    Livotto, PR
    [J]. CHEMICAL PHYSICS, 2000, 253 (2-3) : 165 - 170
  • [9] PYROLYSIS OF C6H6
    COLKET, MB
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 191 : 40 - FUEL
  • [10] PHOTODEPLETION SPECTROSCOPY ON CHARGE RESONANCE BAND OF (C6H6)2+ AND (C6H6)3+
    OHASHI, K
    NISHI, N
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (07): : 2931 - 2932
12345