Synthesis and self-assembling behavior of a porphyrin bearing multiple meso-conjugated barbiturates

被引：3
|
作者：
Arai, Satoshi [1 ]
Okamura, Toshiya [1 ]
Takeoka, Shinji [1 ]
机构：
[1] Waseda Univ, Dept Life Sci & Med Biosci, Fac Sci & Engn, Shinjuku Ku, Tokyo 1628480, Japan
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 39期
关键词：
Porphyrin; Hydrogen bonding; Self-assembly; Barbituric acid; MOLECULAR RECOGNITION; SCHIFF-BASES; ACID; DERIVATIVES; WATER; TAUTOMERISM; COMPONENTS; FILM;
D O I：
10.1016/j.tetlet.2010.07.139
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient procedure through deprotection of 2,4,6-trimethoxypyrimidine derivative afforded porphyrinato zinc bearing multi-barbiturates acting as multiple hydrogen bonding sites at the meso positions. Addition of excess amphiphilic triaminopyrimidine derivative, as a complementary motif to the barbiturate, in an aqueous solution of porphyrin conjugated with multiple barbiturates at the meso positions resulted in precipitation. The cast film from the chloroform solution of the precipitate indicated the formation of a well-defined porphyrin assembly. (c) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5177 / 5180
页数：4
相关论文
共 50 条
  • [31] Morphology and thermal behavior of self-assembling carbamates
    Moniruzzaman, M
    Goodbrand, B
    Sundararajan, PR
    JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (33): : 8416 - 8423
  • [32] Amphiphilic conjugated thiophenes for self-assembling antenna systems in water
    van Rijn, Patrick
    Savenije, Tom J.
    Stuart, Marc C. A.
    van Esch, Jan H.
    CHEMICAL COMMUNICATIONS, 2009, (16) : 2163 - 2165
  • [33] The influence of π-conjugated moieties on the thermodynamics of cooperatively self-assembling tricarboxamides
    Garcia, Fatima
    Korevaar, Peter A.
    Verlee, Arno
    Meijer, E. W.
    Palmans, Anja R. A.
    Sanchez, Luis
    CHEMICAL COMMUNICATIONS, 2013, 49 (77) : 8674 - 8676
  • [34] Self-Assembling DNA Quadruplex Conjugated to MRI Contrast Agents
    Cai, Jianfeng
    Shapiro, Erik M.
    Hamilton, Andrew D.
    BIOCONJUGATE CHEMISTRY, 2009, 20 (02) : 205 - 208
  • [35] Machine learning and molecular design of self-assembling π-conjugated oligopeptides
    Thurston, Bryce A.
    Ferguson, Andrew L.
    MOLECULAR SIMULATION, 2018, 44 (11) : 930 - 945
  • [36] POLY 53-Synthesis of host and guest polymers and their self-assembling behavior
    Lee, Minjae
    Schoonover, Daniel V.
    Gibson, Harry W.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2008, 235
  • [37] Synthesis, self-assembling and gene delivery potential of a novel highly unsaturated, conjugated cationic phospholipid
    Opstad, Christer L.
    Sliwka, Hans-Richard
    Partali, Vassilia
    Elgsaeter, Arnljot
    Leopold, Philip
    Jubeli, Emile
    Khalique, Nada Abdul
    Raju, Liji
    Pungente, Michael D.
    CHEMISTRY AND PHYSICS OF LIPIDS, 2013, 170 : 65 - 73
  • [38] Advances in the synthesis and application of self-assembling biomaterials
    Bhorkar, Isha
    Dhoble, Abhishek S.
    PROGRESS IN BIOPHYSICS & MOLECULAR BIOLOGY, 2021, 167 : 46 - 62
  • [39] Synthesis and functions of macrocycles utilizing self-assembling
    Houjou, H
    Kanesato, M
    Hiratani, K
    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2004, 62 (03) : 194 - 204
  • [40] THE SYNTHESIS AND CHARACTERIZATION OF A SELF-ASSEMBLING AMPHIPHILIC FULLERENE
    HAWKER, CJ
    SAVILLE, PM
    WHITE, JW
    JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (12): : 3503 - 3505
12345