Determination of impurities in graphite using synchrotron radiation based X-ray fluorescence spectrometry

被引：5
|
作者：
Ghosh, M. [1 ,3 ]
Swain, K. K. [1 ,3 ]
Devi, P. S. Remya [1 ]
Chavan, T. A. [1 ]
Singh, A. K. [2 ]
Tiwari, M. K. [2 ]
Verma, R. [1 ]
机构：
[1] Bhabha Atom Res Ctr, Analyt Chem Div, Bombay, Maharashtra, India
[2] Raja Ramona Ctr Adv Technol, Synchrotrons Utilizat Sect, Indore, Madhya Pradesh, India
[3] Homi Bhabha Natl Inst, Bombay, Maharashtra, India
来源：
APPLIED RADIATION AND ISOTOPES | 2017年 / 128卷
关键词：
Graphite; Impurities; Synchrotron radiation; EDXRF; Internal standard method; ATOMIC EMISSION-SPECTROMETRY; HIGH-PURITY GRAPHITE; ACTIVATION-ANALYSIS; TRACE-ELEMENTS; LA;
D O I：
10.1016/j.apradiso.2017.07.025
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Determination of impurities namely Ca, Mn, Fe, Ni, Zn, Sr and Pb in graphite by energy dispersive X-ray fluorescence spectrometry is described using microfocused synchrotron radiation. The internal standard and standard addition methodologies were adopted for quantification and the results were compared with tube based X-ray fluorescence spectrometry. Analysis of the results by the F and t-tests revealed their statistical equivalence. Synchrotron measurements improved the detection limits by an order of magnitude compared to the tube based technique. Cr and Zr, which were below the quantification limit in tube based technique, were also quantified by synchrotron based technique.
引用
收藏
页码：210 / 215
页数：6
相关论文
共 50 条
  • [1] Synchrotron radiation based X-ray fluorescence analysis
    Sawhney, KJS
    [J]. X-RAY SPECTROSCOPY AND ALLIED AREAS, 1998, : 225 - 230
  • [2] Nondestructive discrimination of red silk single fibers using total reflection X-ray fluorescence spectrometry and synchrotron radiation X-ray fluorescence spectrometry
    Komatsu, Hibiki
    Takahara, Hikari
    Matsuda, Wataru
    Nishiwaki, Yoshinori
    [J]. JOURNAL OF FORENSIC SCIENCES, 2021, 66 (05) : 1658 - 1668
  • [3] Progress of Synchrotron Radiation X-Ray Fluorescence Spectrometry in China and Overseas
    Huang Yu-ying
    Zhong Xin-yu
    [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42 (02) : 333 - 340
  • [4] X-RAY-FLUORESCENCE SPECTROMETRY WITH SYNCHROTRON RADIATION
    KNOCHEL, A
    PETERSEN, W
    TOLKIEHN, G
    [J]. ANALYTICA CHIMICA ACTA, 1985, 173 (JUL) : 105 - 116
  • [5] X-ray fluorescence analysis using synchrotron radiation (SYXRF)
    Haller, M
    Knochel, A
    [J]. JOURNAL OF TRACE AND MICROPROBE TECHNIQUES, 1996, 14 (03): : 461 - 488
  • [6] Determination of selenium in rat brain by synchrotron radiation X-ray fluorescence
    Schulmann-Choron, N
    Chevallier, P
    de Ceaurriz, J
    Souleau, C
    [J]. ANALUSIS, 2000, 28 (04) : 316 - 323
  • [7] Nondestructive analysis of silver in gold foil using synchrotron radiation X-ray fluorescence spectrometry
    Kasamatsu, M
    Suzuki, Y
    Nakanishi, T
    Shimoda, O
    Nishiwaki, Y
    Miyamoto, N
    Suzuki, S
    [J]. ANALYTICAL SCIENCES, 2005, 21 (07) : 785 - 787
  • [8] Nondestructive Analysis of Silver in Gold Foil Using Synchrotron Radiation X-ray Fluorescence Spectrometry
    Masaaki Kasamatsu
    Yasuhiro Suzuki
    Toshio Nakanishi
    Osamu Shimoda
    Yoshinori Nishiwaki
    Naoki Miyamoto
    Shinichi Suzuki
    [J]. Analytical Sciences, 2005, 21 : 785 - 787
  • [9] Determination of beryllium by using X-ray fluorescence spectrometry
    Zawisza, Beata
    [J]. ANALYTICAL CHEMISTRY, 2008, 80 (05) : 1696 - 1701
  • [10] Reference-free X-ray spectrometry based on metrology using synchrotron radiation
    Beckhoff, Burkhard
    [J]. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2008, 23 (06) : 845 - 853
12345