Glass-forming ability and crystallization behavior of Ti-Cu-Ni-Sn-M (M=Zr, Mo, and Ta) metallic glasses

被引：23

作者：

He, G

Eckert, J

Hagiwara, M

机构：

[1] IFW Dresden, Inst Met Werkstoffe, D-01171 Dresden, Germany

[2] Natl Inst Mat Sci, Light Mat Grp, Tsukuba, Ibaraki 3050047, Japan

[3] Tech Univ Darmstadt, FB Mat & Geowissensch 11, FG Phys Met Kunde, D-64287 Darmstadt, Germany

来源：

JOURNAL OF APPLIED PHYSICS | 2004年 / 95卷 / 04期

关键词：

D O I：

10.1063/1.1643776

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

The kinetics of the glass transition and the crystallization behavior of Ti-Cu-Ni-Sn-M (M=Zr,Mo,Ta) glassy alloys were investigated by differential scanning calorimetry and x-ray diffraction. The glass-forming ability (GFA) of the glasses was analyzed in terms of the fragility concept and the width of the supercooled liquid region. The Ti-base glasses studied were found to have lower GFA than Zr, Pd, La, Fe, Mg-base bulk metallic glasses (BMGs), but to be comparative GFA to Ni- and Au-base BMGs. Higher Mo content or higher Ti-Ta content in the alloys lowers the GFA. The chemical complexity and multiphase crystallization requiring long-range atomic diffusion may contribute to the thermal stability of the supercooled liquid against crystallization. The products of crystallization of the glasses include bcc beta-Ti(M) solid solution and Ti2Ni and Ti2Cu intermetallics. (C) 2004 American Institute of Physics.

引用

页码：1816 / 1821

页数：6

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