Phosphonodithioformates: Efficient three-component coupling of dialkyl phosphites, carbon disulfide, and alkyl halides in the presence of cesium carbonate and tetrabutylammonium iodide

被引：10
|
作者：
Fox, DL [1 ]
Whitely, NR [1 ]
Cohen, RJ [1 ]
Salvatore, RN [1 ]
机构：
[1] Western Kentucky Univ, Dept Chem, Bowling Green, KY 42101 USA
来源：
SYNLETT | 2003年 / 13期
关键词：
alkylations; alkyl halides; cesium carbonate; phosphonodithioformate; phosphorus;
D O I：
10.1055/s-2003-41482
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A mild one-pot, three-component coupling reaction uniting a dialkyl phosphite, carbon disulfide (CS2) and an alkyl halide for the mild and efficient synthesis of phosphonodithioformates using cesium carbonate (Cs2CO3) and tetrabutylammonium iodide (TBAI) was developed. Various dialkyl phosphites were examined using a diverse array of alkyl halides, and these improved reaction conditions were found to be highly selective producing the title compounds exclusively in moderate to high yields.
引用
收藏
页码：2037 / 2041
页数：5
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