Copper-Catalyzed Three-Component Synthesis of β-Hydroxysulfides from Styrene Oxide, Aryl Iodide, and Carbon Disulfide

被引：0
|
作者：
Yu, Enbo [1 ]
Li, Jun [1 ]
Wang, Yue [1 ]
Chen, Ya [1 ]
Xiao, Fuhong [1 ]
Deng, Guo-Jun [1 ,2 ]
机构：
[1] Xiangtan Univ, Key Lab Green Organ Synth & Applicat Hunan Prov, Key Lab Environm Friendly Chem & Applicat, Minist Educ,Coll Chem, Xiangtan 411105, Peoples R China
[2] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 89卷 / 13期
基金：
中国国家自然科学基金;
关键词：
ONE-POT SYNTHESIS; C-S BOND; ALKENES; SULFUR; DERIVATIVES; HYDROXYSULFURIZATION; ACTIVATION; OLEFINS;
D O I：
10.1021/acs.joc.4c00276
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A copper-catalyzed three-component coupling reaction of styrene oxide, aryl iodide, and carbon disulfide for the construction of beta-hydroxysulfides has been developed. In this process, readily available CS2 was used as the sulfur source to construct C-S bonds for the synthesis of phenyl-beta-hydroxysulfides and (benzo[d]thiazol)-beta-hydroxysulfides. This process features mild reaction conditions, simple operation, and wide substrate scope (>50 examples).
引用
收藏
页码：9287 / 9297
页数：11
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