Compositional and structural control of tenebrescence

被引：23

作者：

Williams, Edward R. ^{[1
]}

Simmonds, Andrew ^{[1
]}

Armstrong, Jennifer A. ^{[1
]}

Weller, Mark T. ^{[1
]}

机构：

[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2010年 / 20卷 / 48期

基金：

英国工程与自然科学研究理事会;

关键词：

DIFFRACTION; HACKMANITE; SODALITES;

D O I：

10.1039/c0jm02066d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of various compositional substitutions on the colour of long-lived F-centres in the sodalite structure has been investigated by the synthesis and characterisation of several phases of the general composition A(8)[M'M '' O-4](6)[X,S](2). The visible-region absorption spectrum of the excited state, formed by 256 nm irradiation of the as-synthesised materials, shows a broad absorption whose position correlates with the dimensions of the sodalite cage occupied by the excited electron.

引用

页码：10883 / 10887

页数：5

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