Physical-chemical and catalytic properties of deposited MoO3 and V2O5

被引：7
|
作者：
Sydorchuk, V. [1 ]
Makota, O. [2 ]
Khalameida, S. [1 ]
Bulgakova, L. [2 ]
Skubiszewska-Zieba, J. [3 ]
Leboda, R. [3 ]
Zazhigalov, V. [1 ]
机构：
[1] NAS Ukraine, Inst Sorpt & Problems Endoecol, UA-03164 Kiev, Ukraine
[2] Lviv Natl Polytech Univ, Inst Chem & Chem Technol, UA-79013 Lvov, Ukraine
[3] Marie Curie Sklodowska Univ, Fac Chem, PL-20031 Lublin, Poland
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2012年 / 108卷 / 03期
关键词：
Vanadium and molybdenum oxides; Deposition; Dry milling; XRD; Epoxidation; MECHANOCHEMICAL TREATMENT; MOLYBDENUM; VANADIUM; ALUMINA;
D O I：
10.1007/s10973-011-1895-9
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The deposition of molybdenum and vanadium oxides onto fumed silica, titania, and alumina as supports through dry milling has been carried out. The structure of prepared compositions has been investigated by means of XRD, DTA-TG, FTIR, and UV-Vis spectroscopy, nitrogen adsorption. The deposited crystal phases are sufficiently uniformly distributed on support surface. The supported oxides are subjected to dispersion in process of milling to the state of oligomeric or isolated species. Milled bulk and deposited MoO3 (first of all, on alumina) possesses improved catalytic performance in process of epoxidation of 1-octene. Vanadium pentoxide also has higher activity in this process.
引用
收藏
页码：1001 / 1008
页数：8
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